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Non-Equilibrium Manufacturing for High-Energy-Input Solid-State Battery Materials.

Hao Shen1, Zhanhui Jia1, Yuyang Zhang1

  • 1State Key Laboratory for Mechanical Behavior of Materials & National Innovation Platform (Center) for Industry-Education Integration of Energy Storage Technology & School of Chemical Engineering and Technology, Xi'an Jiaotong University, Xi'an, 710049, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
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Summary

Rapid heating methods offer a safer, more efficient way to manufacture all-solid-state lithium batteries (ASSLBs). These techniques accelerate production and improve material quality for advanced energy storage.

Keywords:
all‐solid‐state Li batterieshigh‐energy beam heatinghigh‐energy‐input non‐equilibrium processoxide‐based electrolytes and cathodessolid‐state synthesis and sintering

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • All-solid-state lithium batteries (ASSLBs) promise enhanced safety and energy density.
  • Conventional manufacturing of ASSLB components (e.g., solid-state electrolytes, cathodes) involves energy-intensive, slow thermal treatments.
  • These traditional methods can lead to material degradation and limit productivity.

Purpose of the Study:

  • To review recent advances in rapid, non-equilibrium manufacturing strategies for oxide-based ASSLB components.
  • To analyze the thermodynamic principles, electrochemical impacts, and mechanical effects of these novel techniques.
  • To explore the potential of fast, localized processing for industrial-scale ASSLB production.

Main Methods:

  • Review of emerging rapid heating technologies: flash sintering, Flash Joule heating, and microwave-assisted sintering.
  • Analysis of non-equilibrium thermodynamic pathways for material synthesis and densification.
  • Evaluation of high-energy beam methods for localized, rapid processing.

Main Results:

  • Rapid heating accelerates processing, enhances electrolyte density, and suppresses microstructural degradation.
  • Non-equilibrium methods reduce energy consumption and improve material properties like configuration entropy.
  • These techniques are applicable to solid-state electrolytes, cathodes, and co-sintered components.

Conclusions:

  • Rapid, non-equilibrium manufacturing is crucial for developing high-performance ASSLBs.
  • These advanced fabrication methods offer significant advantages in energy efficiency, productivity, and material quality.
  • Further exploration of scalability and industrial relevance is needed for widespread adoption.