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Nanolite cargo evolution in trachybasaltic glass comparing magnetite and augite
Michele Cassetta1,2,3, Gian Carlo Capitani4, Rajat Chaudhary5
1Department of Earth Sciences, University of Torino, 10125, Turin, Italy. michele.cassetta@unito.it.
Scientific Reports
|November 7, 2025
Summary
This study reveals how thermal treatments control crystallization in volcanic glass, altering magnetic and mechanical properties. Tailoring crystal content impacts material strength and crack resistance.
Area of Science:
- Geoscience
- Materials Science
- Solid State Physics
Background:
- Volcanic glasses undergo natural crystallization influenced by thermal history.
- Understanding this process is key to predicting material properties and failure mechanisms.
Purpose of the Study:
- To investigate the link between crystallization, magnetic/mechanical properties, and crack formation in trachybasaltic glass.
- To explore how different thermal treatments affect these properties.
Main Methods:
- Differential scanning calorimetry (DSC)
- Raman spectroscopy
- X-ray powder diffraction (XRD)
- Transmission electron microscopy (TEM)
- Vibrating sample magnetometry (VSM)
- Vickers indentation
Main Results:
- Single-step annealing (850°C) rapidly formed nanocrystals, boosting mechanical strength and inducing ferromagnetism.
- Two-step annealing (750°C → 850°C) promoted gradual magnetite formation, enhancing hardness and reducing cracks, with a paramagnetic response.
- Altering crystal content directly influenced hardness, crack resistance, and magnetic behavior.
Conclusions:
- Thermal treatment is a critical factor in controlling the properties of volcanic glasses.
- Natural volcanic heating patterns may drive crystallization, influencing material failure dynamics.
- This research offers insights into the relationship between geological processes and material science.
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