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Reduction Effect of Extra Biochar on PAHs Originating from Corn Stover Pyrolysis.

Lijie Li1, Xiuli Shen1, Haibo Meng1

  • 1Key Laboratory of Energy Resource Utilization from Agriculture Residue, Ministry of Agriculture and Rural Affairs, Academy of Agricultural Planning and Engineering, Beijing 100125, China.

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Summary

Adding extra biochar to corn stover pyrolysis significantly reduced polycyclic aromatic hydrocarbons (PAHs) in biochar at 500°C. This catalytic approach offers a promising, low-cost method for cleaner biochar production.

Keywords:
biocharcorn stoverextra biocharpolycyclic aromatic hydrocarbons (PAHs)residual tar

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Area of Science:

  • Environmental Science
  • Chemical Engineering
  • Materials Science

Background:

  • Increasing environmental concerns regarding polycyclic aromatic hydrocarbons (PAHs) in biochar production necessitate optimized, cost-effective pyrolysis processes.
  • Developing efficient methods to minimize PAHs in biochar and residual tar is crucial for sustainable biomass utilization.

Purpose of the Study:

  • To investigate the catalytic effect of extra biochar on reducing PAHs during corn stover pyrolysis.
  • To evaluate the impact of biochar addition on PAH concentrations in both the final biochar product and residual tar.
  • To establish the reaction mechanism for PAH reduction using biochar as a catalyst.

Main Methods:

  • Corn stover was pyrolyzed in a fixed-bed reactor at temperatures of 500, 600, and 700 °C.
  • Biochar produced at these temperatures was added as a catalyst by stacking it above the feedstock.
  • Concentrations of PAHs in biochar and residual tar were analyzed; physicochemical properties of the catalytic biochar were also examined.

Main Results:

  • Stacking extra biochar significantly reduced PAHs in corn stover biochar and residual tar at 500 °C (e.g., biochar PAHs from 9.14 mg/kg to 3.66 mg/kg).
  • PAH concentrations in biochar decreased substantially, while residual tar PAHs also showed reduction at 500 °C.
  • Conversely, PAH concentrations in residual tar increased at higher temperatures (600 °C and 700 °C).

Conclusions:

  • The addition of extra biochar effectively reduces PAHs in the resulting biochar, particularly at moderate pyrolysis temperatures (500 °C).
  • This catalytic approach presents a viable strategy for mitigating PAH contamination in biochar production.
  • Further optimization is needed to address PAH reduction in the entire pyrolysis process, especially at higher temperatures.