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Updated: Jan 11, 2026

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Oxidation-induced σ-aromaticity in halogenated cycloalkanes.

Slavko Radenković1, Slađana Đorđević1

  • 1University of Kragujevac, Faculty of Science, P. O. Box 60, 34000 Kragujevac, Serbia. slavkoradenkovic@kg.ac.rs.

Physical Chemistry Chemical Physics : PCCP
|November 18, 2025
PubMed
Summary

Neutral halogenated cycloalkanes can become σ-aromatic dicationic species via oxidation. These novel compounds exhibit significant σ-electron delocalization in halogen rings, resembling known aromatic systems.

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