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Heating rate gradient drives mesostructural dynamics in solid propellant under nonequilibrium conditions
Zhi Jiang1, Tianhao Wang1, Weichen Sheng1
1School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
Rapid heating rates, not bulk temperature, control material changes under extreme conditions. This study reveals how local heating dictates void formation and fragmentation in composites, impacting ignition and combustion.
Area of Science:
- Materials Science
- Chemical Engineering
- Physics
Background:
- Heterogeneous composite materials undergo rapid structural evolution under extreme thermal conditions, impacting aerospace and structural applications.
- Current experimental methods cannot observe dynamic structural changes under realistic nonequilibrium thermal fronts.
- Existing theoretical models often assume equilibrium conditions, limiting their predictive accuracy.
Purpose of the Study:
- To develop and demonstrate a novel experimental system for observing mesoscale structural evolution in composite materials under controlled, rapid, nonequilibrium heating.
- To investigate the influence of local heating rates on void formation, fragmentation, and ignition pathways.
- To provide experimental validation for theoretical models of material behavior under extreme thermal loads.
Main Methods:
- Development of a gradiated fast-heating system with precise control over heating rate gradients (>20 °C/s) in submillimeter regions.
- Integration of sequential synchrotron X-ray tomography and radiography for direct visualization of internal structural evolution.
- Analysis of microsecond-to-millisecond timescale transformations from pyrolysis through ignition to burnout.
Main Results:
- Local heating rates, not bulk temperatures, were identified as the primary drivers of void formation and fragmentation dynamics.
- High local heating rates led to rapid void nucleation and reticulated porous network formation in the binder phase, occurring significantly faster than interfacial void evolution.
- Heterogeneous component interactions fragmented the metallic network, creating ignition hotspots that controlled combustion initiation and propagation.
Conclusions:
- Mesoscale structural evolution in composite materials under extreme nonequilibrium heating is critically dependent on local heating rates and kinetic processes.
- The developed experimental approach enables direct observation of complex transformation pathways, advancing the understanding of material behavior under extreme conditions.
- Findings provide crucial data for validating and improving theoretical models for predicting composite material performance in demanding applications.
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