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Updated: Jan 10, 2026

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
Published on: September 5, 2018
AMOchar: an amorphous MnOx functionalized biochar to stabilize metal(loid)s in soil and optimize phytostabilization
Sayyeda Hira Hassan1,2, Zubda Zahid3, Petr Ouředníček1
1Department of Environmental Geosciences, Faculty of Environmental Sciences, Czech University of Life Sciences Prague, Prague 6, Czech Republic.
Surface modification of biochar with manganese oxides improves metal immobilization. Sucrose-based manganese oxide biochar (BCS) is more stable, reducing metal transfer to plants and enhancing phytostabilization.
Area of Science:
- Environmental Science
- Soil Science
- Materials Science
Background:
- Biochar (BC) is used for metal(loid) immobilization, but its effectiveness varies.
- Surface modifications, like amorphous manganese oxides (AMOchars), enhance immobilization but can cause manganese leaching.
Purpose of the Study:
- To evaluate manganese oxide fixation on biochar for reducing metal(loid) transfer to plants.
- To compare molasses-based (BCM) and sucrose-based (BCS) AMOchars to identify the optimal reducing agent.
Main Methods:
- Synthesized two AMOchars using molasses and sucrose as reducing agents.
- Monitored soil solution to assess pH, metal(loid) immobilization, and leaching.
- Analyzed metal(loid) uptake in plants to evaluate phytostabilization efficiency.
Main Results:
- All biochar materials increased soil pH and immobilized Cd, Pb, and Zn.
- AMOchars enhanced Cd and Zn immobilization but released dissolved organic carbon, As, Cu, and Mn.
- BCS showed improved immobilization and reduced metal transfer to plants compared to BCM.
Conclusions:
- Manganese oxide fixation on biochar, particularly using sucrose, effectively improves phytostabilization.
- Sucrose-based AMOchar is a more stable material, reducing organic carbon leaching and plant toxicity.
- This study advances biochar modification knowledge for practical field application in aided phytostabilization.
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