Self-Referencing Photothermal Common-Path Interferometry to Measure Absorption of Si₃N₄ Membranes for Laser-Light...

Laser-light sails are a spacecraft concept, wherein lightweight "sails" are propelled by high-intensity lasers. We investigated the near-infrared absorption of free-standing membranes of stoichiometric silicon nitride (Si₃N₄), a candidate sail material. To resolve the small but nonzero optical loss, we used photothermal common-path interferometry (PCI), for which we developed a self-referencing modality where a PCI measurement is performed twice: once on a bare membrane, and a second time with monolayer graphene deposited on the membrane. The graphene increases the absorption of the sample by orders of magnitude, such that it can be measured by ellipsometry without significantly affecting the thermal properties. We measured the absorption coefficient of Si₃N₄ to be (1.5-3) × 10^-2 cm^-1 at 1064 nm, making it a suitable sail material for laser intensities as high as ∼10 GW/m². By comparison, silicon-rich "low stress" SiN _x (x ∼ 1), with a measured absorption coefficient of approximately 8 cm^-1, is unlikely to survive such high laser intensities. Our self-referencing technique enables the testing of low-loss membranes of various materials for laser sails and other applications.