Highly sensitive electrochemical detection of hazardous 2,4-dinitrophenylhydrazine using MgCo-TiO₂/g-C₃N₄...

In this study, MgCo-TiO₂/g-C₃N₄ heterostructure nanocomposites were successfully synthesized for the electrochemical detection of 2,4-dinitrophenylhydrazine. The MgCo-TiO₂/C₃N₄ heterostructure nanocomposites were synthesized by preparing bimetal (Mg-Co)-doped TiO₂ via a microwave-assisted sol gel method, followed by a thermal approach to coat it onto g-C₃N₄ nanosheets. The morphology, structure, composition and optical and electrochemical properties of the fabricated heterostructure nanocomposites were characterized by various analytical techniques including PXRD, UV-DRS, VB-XPS, PL, HRTEM, FESEM-EDX, FT-IR, EIS and CV. To develop an electrochemical sensor for 2,4-dinitrophenylhydrazine (2,4-DNPH), the MgCo-TiO₂/g-C₃N₄ heterostructure nanocomposites were coated onto a glassy carbon electrode (GCE) by a drop-casting method. MgCo-TiO₂/g-C₃N₄/GCE showed an excellent electroanalytical response for the oxidation of 2,4-DNPH in a lower pH environment. MgCo-TiO₂/g-C₃N₄/GCE exhibited excellent selectivity, sensitivity (589.13 µA µM^-1 cm^-2), and a lower limit of detection (0.06 µM) in a wide linear range (0.1-0.9 µM) under optimized conditions. Furthermore, the sensor exhibited high repeatability (RSD 1.38%), reproducibility (RSD 3.57%), stability and recovery in real sample analysis.