Heavy Metal Contamination and Risk Assessment in Soil-Wheat/Corn Systems near Metal Mining Areas in Northwestern...

Heavy metals in farmland soils pose severe threats to agricultural productivity and food safety. To investigate contamination in the soil-wheat/corn system, 24 sets of adjacent farmland soil, wheat, and corn plant samples were collected near metal smelting facilities in Jinchang City, a typical urban oasis in northwestern China. Concentrations of Ni (nickel), Cu (copper), and Co (cobalt) were measured. Results indicated mean soil concentrations of 143.66 mg kg^-1 (Ni), 130.00 mg kg^-1 (Cu), and 24.04 mg kg^-1 (Co), all exceeding background values for Gansu Province, confirming that the sampling sites exhibit varying degrees of contamination with Ni, Cu, and Co. Correlation analyses revealed strong intermetal relationships (Ni, Cu, Co; p < 0.01), while spatial distribution patterns showed that Ni in wheat and corn grains closely mirrored soil Ni distribution. The bio-concentration factor (BCF) for wheat roots surpassed that of corn roots, highlighting wheat's greater susceptibility to heavy metal uptake. Heavy metal levels in crop organs exceeded limits set by the Safety Guidelines for Feed Additives. Geo-accumulation indices and potential ecological risk assessments demonstrated substantial metal accumulation and varying ecological risks, with contamination levels ranked as Cu > Ni > Co. Non-carcinogenic hazard indices indicated elevated health risks for children consuming locally grown wheat and corn. This study provides a scientific foundation for crop rotation strategies and soil remediation in the region.