Source-Oriented Health Risk Assessment of Potentially Toxic Elements in the Water-Soil-Crop System Using Monte Carlo...

Mining and smelting release potentially toxic elements (PTEs) that threaten ecosystems and public health. However, comprehensive risk assessments of PTEs across environmental media near mining areas remain scarce. The Laoguan River Basin is located in southwestern Henan Province, China. It lies within the water source area of China's South-to-North Water Diversion Middle Route Project. This area has high geographic and ecological importance. In this study, we analyzed the pollution characteristics of PTEs in the water-soil-crop system. We also performed a source-oriented health risk assessment by integrating Monte Carlo simulation with source apportionment. According to this study, Mo and Sb were the predominant contaminants in soils and water. Pb, Cr, and Ni were elevated in crops. The health risk assessment indicated that PTEs in surface water were at acceptable levels. In contrast, PTEs in soils pose both non-carcinogenic and carcinogenic risks, particularly to children. The estimated risks were 1% (non-carcinogenic) and 64% (carcinogenic), with ingestion as the primary exposure pathway. Source apportionment showed that the surface water pollution was mainly linked to diverse mining activities. Soil pollution was jointly influenced by the geological background and mining and agricultural activities. Crop pollution was primarily associated with mining and agricultural activities. Geological background and mining were the main driving factors of the increased health risks for children. They accounted for 83% of the non-carcinogenic risk and 79% of the carcinogenic risk. Overall, these results are crucial for pollution control, safeguarding public health and safety, and promoting balanced economic and ecological development.