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Related Concept Videos

P-N junction01:11

P-N junction

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A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
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Ambient Method for the Production of an Ionically Gated Carbon Nanotube Common Cathode in Tandem Organic Solar Cells
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Resolving Ternary Morphology for High-Performance Thickness-Insensitive Organic Solar Cells.

Heng Liu1, Yuhao Li1,2, Zhaoyang Nie3

  • 1Department of Physics, The Chinese University of Hong Kong, New Territories, Hong Kong 999077, China.

ACS Applied Materials & Interfaces
|November 28, 2025
PubMed
Summary

High-performance organic solar cells (OSCs) achieve 17.7% efficiency with thicker active layers by adding BTR-Cl. This improves connectivity and performance, overcoming limitations for large-scale manufacturing.

Keywords:
carrier transport connectivitygrazing-incidence small-angle neutron scatteringshort-range aggregationtargeted deuterationternary strategythick-film organic solar cells

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Area of Science:

  • Materials Science
  • Organic Electronics
  • Photovoltaics

Background:

  • High-performance organic solar cells (OSCs) face challenges with active layer thickness tolerance.
  • This limitation hinders large-scale printing and cost-effective module manufacturing.

Purpose of the Study:

  • To develop efficient ternary organic solar cells with improved thickness tolerance.
  • To elucidate the morphological origins of enhanced performance in thick-film OSCs.

Main Methods:

  • Fabrication of ternary OSCs using PM6/Y6 blend films incorporating small-molecule donor BTR-Cl.
  • Utilizing targeted deuteration of Y6 and BTR-Cl.
  • Employing grazing-incidence small-angle neutron scattering (GISANS) to resolve blend film morphology.

Main Results:

  • Achieved a photoconversion efficiency of 17.7% at an active layer thickness of 300 nm.
  • Observed enhanced short-range aggregation of Y6 and BTR-Cl, improving inter-domain connectivity.
  • Demonstrated enhanced carrier mobility and suppressed space charge accumulation.

Conclusions:

  • Incorporating BTR-Cl significantly improves the thickness tolerance of OSCs.
  • Amorphous nanomorphology plays a critical role in carrier transport connectivity and device performance.
  • Targeted deuteration combined with GISANS is effective for analyzing multicomponent OSC active layers.