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Redox Reactions01:24

Redox Reactions

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Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
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Metal-Ligand Bonds02:51

Metal-Ligand Bonds

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The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Redox Equilibria: Overview01:23

Redox Equilibria: Overview

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A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
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Redox Titration: Other Oxidizing and Reducing Agents01:26

Redox Titration: Other Oxidizing and Reducing Agents

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Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and K2Cr2O7. The choice of oxidizing titrants depends on factors like stability, cost, analyte strength, and reaction rate between the analyte and titrant. KMnO4 is a strong oxidizing titrant that reduces from Mn(VII) to Mn(II) in a highly acidic solution, simultaneously oxidizing the analyte to a higher oxidation state. In this case, KMnO4 acts as a...
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Related Experiment Video

Updated: Jan 9, 2026

Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
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Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks

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Water-resistant redox-active metal-organic framework.

Ryota Akai1, Showa Kitajima1, Kohei Okubo1

  • 1Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi, Japan.

Nature Communications
|December 1, 2025
PubMed
Summary

This study introduces a stable redox-active metal-organic framework (RAMOF) for electrochemical applications. This novel RAMOF demonstrates exceptional durability and theoretical capacity in acidic aqueous electrolytes.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) show promise for electrochemical applications.
  • MOFs typically exhibit poor structural stability in aqueous solutions, limiting their use in charge-storage devices.

Purpose of the Study:

  • To develop a structurally robust and electrochemically active metal-organic framework (MOF) for aqueous charge-storage applications.
  • To demonstrate the potential of redox-active MOFs (RAMOFs) in harsh acidic aqueous electrolytes.

Main Methods:

  • Synthesis of a novel redox-active metal-organic framework (RAMOF) utilizing strong Zr-O bonds.
  • Electrochemical characterization of the RAMOF in acidic aqueous electrolytes.
  • Fabrication and testing of an aqueous MOF-air rechargeable battery.

Main Results:

  • The RAMOF demonstrated excellent structural stability and reversible charge storage with near-theoretical capacity in acidic aqueous electrolytes.
  • Achieved high durability (>98% over 100 cycles) and Coulombic efficiency (99.9%) due to high crystallinity and proton conductivity.
  • Successfully fabricated and tested a durable aqueous MOF-air rechargeable battery.

Conclusions:

  • Redox-active metal-organic frameworks (RAMOFs) offer a viable solution for stable electrochemical applications in aqueous environments.
  • The demonstrated material recycling highlights the sustainability of RAMOFs.
  • RAMOFs present significant advantages for aqueous charge-storage devices and energy storage systems.