Interlayer bismuthene as a charge-transporter improves the photoelectrochemical water oxidation activity of a bismuth vanadate metal-organic framework
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Updated: May 6, 2026

Preparation of Polyoxometalate-based Photo-responsive Membranes for the Photo-activation of Manganese Oxide Catalysts
Published on: August 7, 2018
Deepak Kumar1, Sagnik Mukherjee1, Arindam Indra1
1Department of Chemistry, Indian Institute of Technology (BHU), Varanasi, UP-221005, India. arindam.chy@iitbhu.ac.in.
Abstract:
The introduction of bismuthene as a charge transport layer between BiVO4 and a cocatalyst (Ni-metal-organic framework, Ni-MOF) improves the photoelectrochemical water oxidation activity. The photoanode BiVO4/Bi/Ni-MOF produces a photocurrent of 4.71 (±0.2) mA cm-2 (at 1.23 V vs. RHE), which is 2.5 and 1.25 times higher than those of bare BiVO4 and BiVO4/Ni-MOF, respectively.
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