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Updated: Jan 9, 2026

Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
Published on: November 30, 2020
Electrochemical upcycling biomass-derived methyl 2-furoate and CO2 into monomers for recyclable polyesters
Pengfei Shi1,2, Xinyu Chai3, Yuefeng Wang2
1School of Electronic Information and Electrical Engineering, Shanghai Jiao Tong University, Shanghai, P. R. China.
Abstract:
We developed a site-selective electrochemical carboxylation strategy that converts biomass-derived methyl 2-furoate into dimethyl furan-2,5-dicarboxylate using CO2 as a sustainable C1 source. The reaction afforded the target monomer in 27% yield with excellent regioselectivity (>99%). Gram-scale synthesis, polymerization, and methanolysis recycling demonstrated efficient production and recyclability of furan-based polyesters.
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