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Updated: Jan 9, 2026
Negative Additive Manufacturing of Complex Shaped Boron Carbides
Published on: September 18, 2018
Atomic-Level Insights into Thermal Carbonization of Ethynyl-Containing Boron Compounds
Kentaro Ohkura1, Satoshi Hayakawa2, Naoki Takahashi3
1Research Institute for Interdisciplinary Science, Okayama University, 3-1-1, Tsushimanaka, Kita-ku, Okayama, 700-8530, Japan.
None:
This study reports the design, synthesis, and characterization of boron-doped carbon (BDC) derived from a triethynylborane-pyridine complex. Triethynylborane is stabilized by coordination with pyridine, facilitating its synthesis and handling in ambient conditions. The complex is subjected to thermal treatment at various temperatures to form BDC. Powder XRD and single-crystal XRD analyses reveal that BDC prepared at 200 °C retains an ordered structure, while higher temperatures induce alkyne structural changes without significant weight or surface area alterations. Coin cells are assembled using BDC as the anode, demonstrating unique Li-ion and Na-ion storage properties distinct from graphite. These results suggest that the BDC reflects the precursor's crystal structure, enabling novel electrochemical behavior. These findings offer insight into the development of advanced BDC materials for energy storage applications.
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