Valley splitting correlations across a silicon quantum well containing germanium
Jonathan C Marcks1,2,3, Emily Eagen4, Emma C Brann4
1Q-NEXT, Argonne National Laboratory, Lemont, IL, USA. jmarcks@anl.gov.
Nature Communications
|December 6, 2025
Summary
Researchers studied valley splitting variations in silicon-germanium quantum dots for quantum computing. They found correlations consistent with alloy disorder, crucial for designing scalable quantum devices.
Area of Science:
- Quantum Computing
- Materials Science
- Semiconductor Physics
Background:
- Electron spin qubits in SiGe/Si/SiGe heterostructures are key for quantum computers.
- Near-degenerate electron valley states in silicon quantum wells reduce qubit fidelity.
- Valley splitting is sensitive to microscopic disorder in SiGe alloys and interfaces.
Purpose of the Study:
- Investigate valley splitting variations in a 1D quantum dot array within a SiGe/Si/SiGe heterostructure.
- Understand the impact of alloy disorder on valley splitting at different length scales.
- Inform scalable quantum device design for silicon-based quantum computers.
Main Methods:
- Fabrication of a 1D quantum dot array in a Si$_{0.972}$Ge$_{0.028}$ quantum well by Intel.
- Experimental study of valley splitting variations across the quantum dot array.
- Analysis of correlations in valley splitting at sub-100 nm and >1 μm length scales.
Main Results:
- Observed correlations in valley splitting at both single-gate (sub-100 nm) and device (>1 μm) length scales.
- Results align with theoretical predictions and simulations dominated by alloy disorder.
- Demonstrated the mesoscopic nature of valley splitting variations in Si/SiGe heterostructures.
Conclusions:
- Alloy disorder significantly influences valley splitting in SiGe quantum wells.
- Understanding these mesoscopic variations is essential for improving qubit fidelity.
- The findings provide critical insights for the scalable manufacturing of silicon quantum processors.
Related Concept Videos
Biasing of Metal-Semiconductor Junctions
521
Biasing metal-semiconductor junctions involves applying a voltage across the junction. Specifically, the metal is connected to a voltage source, while the semiconductor is grounded. This technique is essential for controlling the direction and magnitude of current flow in electronic devices, including diodes, transistors, and photovoltaic cells.
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
In Schottky junctions, where the semiconductor is n-type, applying a positive voltage to the metal relative to the semiconductor reduces its Fermi...
521
Schottky Barrier Diode
908
Schottky barrier diodes are specialized semiconductor devices characterized by their unique construction. This construction involves combining a metal layer with a moderately doped n-type semiconductor material. This combination leads to the formation of a Schottky barrier, a pivotal element that defines the diode's operational characteristics. The core functionality of Schottky barrier diodes is their capacity to allow current to flow in only one direction due to their distinctive...
908
Semiconductors
1.4K
There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
1.4K
Metal-Semiconductor Junctions
874
The contact of metal and semiconductor can lead to the formation of a junction with either Schottky or Ohmic behavior.
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
Schottky Barriers
Schottky barriers arise when a metal with a work function (Φm) contacts a semiconductor with a different work function (Φs). Initially, electrons transfer until the Fermi levels of the metal and semiconductor align at equilibrium. For instance, if Φm > Φs, the semiconductor Fermi level is higher than the metal's before contact. The...
874
Fermi Level Dynamics
626
The vacuum level denotes the energy threshold required for an electron to escape from a material surface. It is usually positioned above the conduction band of a semiconductor and acts as a benchmark for comparing electron energies within various materials.
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
Electron affinity in semiconductors refers to the energy gap between the minimum of its conduction band and the vacuum level and it is a critical parameter in determining how easily a semiconductor can accept additional electrons.
The work...
626
Biasing of P-N Junction
1.7K
The operation of a p-n junction diode involves various biasing conditions, including forward bias, reverse bias, and equilibrium.
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
In equilibrium, no external voltage is applied across the p-n junction. The depletion region is formed at the junction interface due to the diffusion of carriers, which leaves behind charged dopants, acceptors on the p-side, and donors on the n-side. These immobile charges create an electric field that prevents further diffusion of carriers. The related energy band...
1.7K


