Why strontium baselines should be based on pristine areas only: The disturbing effect of agricultural lime revisited

  • 0Department of Geoscience, Aarhus University, Høegh-Guldbergs Gade 2, 8000, Aarhus C, Denmark.

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Summary

This summary is machine-generated.

Agricultural lime lowers groundwater 87Sr/86Sr ratios in farmland. Pristine areas retain higher ratios, indicating lime

Area Of Science

  • Geochemistry
  • Environmental Science
  • Hydrogeology

Background

  • The 87Sr/86Sr ratio in groundwater is a key geochemical tracer.
  • Understanding anthropogenic impacts on natural strontium isotope signatures is crucial for environmental monitoring.

Purpose Of The Study

  • To investigate the impact of agricultural practices on groundwater 87Sr/86Sr ratios.
  • To differentiate between natural and anthropogenic sources of strontium in meltwater plain environments.

Main Methods

  • Analysis of 87Sr/86Sr ratios in groundwater and vadose zone sand from boreholes.
  • Comparison of isotope ratios in pristine (heath/forest) and agricultural (farmland) areas.
  • Evaluation of potential strontium sources, including agricultural lime and carbonate clasts.

Main Results

  • Groundwater and vadose zone sand exhibit significantly lower 87Sr/86Sr ratios in farmland compared to pristine areas.
  • The observed decrease in 87Sr/86Sr ratios in farmland is attributed to the application of agricultural lime.
  • Strontium from agricultural lime is mobile and not retained in topsoil.

Conclusions

  • Agricultural lime application demonstrably alters groundwater strontium isotope signatures.
  • Pristine areas serve as a better reference for natural strontium baselines.
  • Groundwater and surface water in contact with farmland are unsuitable for establishing natural strontium baselines.