Ultrathin Iridium Nanosheets on Titanium Oxide for High-Efficiency and Durable Proton Exchange Membrane Water...

Reducing iridium (Ir) usage is essential for the commercial viability of proton exchange membrane water electrolysis (PEMWE), where the oxygen evolution reaction (OER) is a major performance and cost bottleneck. Conventional Ir nanoparticles (∼5 nm) suffer from low dispersion and limited surface utilization. Here, we report a catalyst architecture comprising ultrathin Ir nanosheets (Ir NS) supported on spherical TiO₂ particles (Ir NS/TiO₂). The ∼100 nm TiO₂ particles effectively disperses 1-3 μm-wide, sub 2 nm-thick Ir nanosheets, ensuring full surface exposure and continuous electron transport, despite the intrinsically low conductivity of TiO₂. The Ir NS/TiO₂ catalyst exhibits enhanced OER activity and durability in both half-cell and PEMWE single-cell configurations. At an Ir loading of 0.7 mg_Ir cm^-2, Ir NS/TiO₂ achieves 3.6 A cm^-2 at 1.8 V, significantly outperforming commercial Ir nanoparticles (Ir NP, 2.6 A cm^-2). Long-term operation at 1.0 A cm^-2 over 1000 h shows a low voltage decay rate of 0.095 mV h^-1, compared to 0.414 mV h^-1 for Ir NP. Moreover, Ir NS/TiO₂ with an Ir loading amount of 0.5 mg_Ir cm^-2 delivers comparable performance to Ir NP at 1.4 mg_Ir cm^-2. These results present Ir NS/TiO₂ as a highly efficient and durable OER catalyst, supporting its potential for cost-effective, scalable green hydrogen production.