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Unraveling Specific Conditions for a Repeatable Mpemba Effect.

James D Brownridge1, Matthieu Zinet2, Paul Sotta3

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Hot water freezes faster than cold water under specific conditions, confirming the Mpemba effect. This study precisely controlled variables to demonstrate the phenomenon, attributing it to heat transfer differences.

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Area of Science:

  • Physics
  • Physical Chemistry

Background:

  • The Mpemba effect, where hot water freezes faster than cold water, is a debated phenomenon.
  • Previous studies have faced challenges in replication and explanation, leading to controversy.

Purpose of the Study:

  • To robustly demonstrate and investigate the Mpemba effect under controlled conditions.
  • To provide a plausible explanation for the observed phenomenon based on heat transfer.

Main Methods:

  • Simultaneous freezing of hot and cold water samples in a freezer with ice-nucleating agents.
  • Precise temperature recording and elimination of supercooling.
  • Heat transfer simulations based on Newton's law.

Main Results:

  • Hot water samples froze faster and to a greater depth than cold samples, especially with a high initial temperature difference.
  • The onset of crystallization was consistently delayed for hotter samples.
  • Experimental results aligned with heat transfer simulations.

Conclusions:

  • The study confirms the Mpemba effect under specific, controlled experimental conditions.
  • Differences in heat transfer are proposed as the primary mechanism explaining the faster freezing of hot water.
  • This research validates the original findings of Mpemba and Osborne.