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Updated: Jan 8, 2026

The Effect of Charging and Discharging Lithium Iron Phosphate-graphite Cells at Different Temperatures on Degradation
Published on: July 18, 2018
Analysis of thermochemical energy storage in metal carbonates: characterizing cycling-induced degradation
Michael J Adams1, Tae Kyu Kim1, Samuel Pennell2
1George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA. akanksha.menon@me.gatech.edu.
Abstract:
A solid-gas reaction rate modeling framework is applied to characterize degradation in thermochemical materials induced by thermal cycling. Time constants and a kinetic conversion ratio are established for a representative carbonation-calcination reaction, which provides insight into degradation mechanisms and reveals a mitigation strategy by tuning reaction duration.
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