Related Experiment Video
Updated: Jan 8, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Chaos in nonequilibrium two-temperature (Tx, Ty) Nosé-Hoover cell models
Hesam Arabzadeh1, Carol Griswold Hoover2, William Graham Hoover2
1Department of Chemistry, University of Missouri, Columbia, Missouri 65211, USA.
None:
We revisit a two-temperature Nosé-Hoover wanderer particle embedded in a two-dimensional periodic 2 × 2 cell with four smooth repulsive corners at (x, y) = (±1, ±1) to explore chaos with anisotropic thermostatting. The model employs separate thermostats in the x and y directions, enabling controlled deviations from equilibrium. By integrating the full six-dimensional equations of motion and computing the complete Lyapunov spectrum, we confirm chaos and quantify phase-space contraction from the fully resolved six-dimensional Lyapunov spectrum. The total contraction rate, interpreted as entropy production, increases nonlinearly with the thermostat anisotropy, deviating from the quadratic dependence expected from linear-response theory, Λ ∝ δ2. We analyze two functional forms for the entropy-production rate, Λ(δ) (with δ = 0.5 - Ty): (i) a quadratic-plus-quartic expansion, consistent with linear-response expectations, and (ii) a power law, Λ ∝ δ2.44. While the latter captures the low-driving regime slightly better, the former more accurately describes the strongly driven regime and remains consistent with linear-response theory near equilibrium. An empirical linear relation between dissipation and phase-space dimensionality loss is also identified, Λ ≈ (DKY - 6)/3, where DKY is the approximate Kaplan-Yorke dimension. Momentum statistics show a significant non-Gaussian behavior under strong driving. Despite its dissipative nature, the model remains strictly time-reversible, offering a pedagogically rich example of microscopic reversibility coexisting with macroscopic entropy production.
More Related Videos
Related Concept Videos
Non-equilibrium in the Cell
The Nernst Equation
The interconnection between standard cell potentials and various thermodynamic parameters such as the standard free energy change ΔG° and equilibrium constant K has been previously explored. For example, a redox reaction involving zinc(II) and tin(II) ions at 1 M concentration with Eºcell = +0.291 V and ΔG° = −56.2 kJ is spontaneous.
Atomic Nuclei: Nuclear Spin State Population Distribution
Second Law of Thermodynamics
Second Law of Thermodynamics
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.

