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Thermoplastic Polyurethane-Based Composite Film with a Hierarchical Porous Structure for Radiative Cooling and
Chao Shi1, Xinyu Tan1,2, Shengyu Chen1
1Hubei Provincial Engineering Research Center for Solar Energy High-Value Utilization and Green Conversion, China Three Gorges University, Yichang, Hubei 443002, P. R. China.
Langmuir : the ACS Journal of Surfaces and Colloids
|December 15, 2025
Summary
This study presents a novel MgO-doped porous film for passive radiative cooling (PRC) and antibacterial applications. The material achieves significant cooling and preserves strawberry freshness for longer periods without external energy input.
Area of Science:
- Materials Science
- Nanotechnology
- Sustainable Energy
Background:
- Passive radiative cooling (PRC) leverages Earth's atmospheric window to dissipate heat.
- Developing materials with combined cooling and antimicrobial properties is crucial for various applications.
Purpose of the Study:
- To develop a high-performance passive radiative cooling material with integrated antibacterial functionality.
- To evaluate the material's cooling efficiency and its effectiveness in food preservation.
Main Methods:
- Fabrication of a porous thermoplastic polyurethane film doped with MgO (PTM) using a water-solvent phase separation method.
- Characterization of optical properties (solar reflectivity, mid-infrared emissivity) and cooling performance.
- Assessment of antibacterial efficacy against Escherichia coli and application in strawberry preservation.
Main Results:
- The PTM film exhibited high solar reflectivity (94%) and mid-infrared emissivity (0.95).
- Achieved an average cooling effect of 14.6 °C under solar radiation (630 W·m-2).
- Demonstrated over 95% inhibition rate against Escherichia coli and extended strawberry freshness by 4-8 °C localized cooling.
Conclusions:
- The developed PTM film offers efficient passive radiative cooling and broad-spectrum antibacterial properties.
- The dual-functionality material shows significant potential for zero-energy cooling and enhanced hygiene in food preservation.
- This technology offers a sustainable solution for extending the shelf life of perishable goods.

