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Robust Full-Life Superhydrophobic Copper Foam/Polymer Porous Composite with Enhanced Electromagnetic Shielding
Xiaorong Liu1, Yi Zhao1, Mingyun He1
1Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China.
Langmuir : the ACS Journal of Surfaces and Colloids
|December 18, 2025
Summary
This study introduces a durable, superhydrophobic copper foam composite for advanced electromagnetic interference shielding. The eco-friendly material maintains shielding effectiveness in harsh conditions, reducing electronic waste.
Area of Science:
- Materials Science
- Nanotechnology
- Environmental Science
Background:
- Smart electronics and 5G technology increase electromagnetic pollution, requiring effective shielding materials.
- Metal foams offer good electromagnetic interference (EMI) shielding but degrade in humid conditions due to corrosion.
- Existing superhydrophobic materials often lack mechanical robustness.
Purpose of the Study:
- To develop a sustainable and robust superhydrophobic composite for advanced EMI shielding.
- To address moisture-induced shielding deterioration and mechanical fragility in traditional materials.
- To create an eco-friendly material without hazardous byproducts.
Main Methods:
- A solvothermal approach was used for in situ growth of porous polymers within a copper foam framework.
- The composite combines copper's structural integrity with the polymer's superhydrophobicity.
- Durability was tested via abrasion, scratching, compression, solvent immersion, and temperature cycling.
Main Results:
- The composite exhibited exceptional superhydrophobic durability (water contact angle >150°, rolling angle <4°) after harsh tests.
- A total shielding effectiveness of 66.9 dB was achieved, increasing to 78.7 dB under compression.
- Electromagnetic shielding performance remained stable after sunlight and wet-heat cycling exposure.
Conclusions:
- The developed composite offers a sustainable and robust solution for EMI shielding in demanding applications.
- The eco-friendly design overcomes limitations of traditional materials, enhancing durability and performance.
- This work presents a new paradigm for designing multifunctional materials with superhydrophobic and electromagnetic properties.

