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Multifunctional CFRP interfacial engineering via 355 nm laser-induced LIPSS.

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    A new laser method creates nanoscale surface textures on polymers for advanced applications. This rapid, single-step process offers precise control and enhances material properties for electronics and coatings.

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    Area of Science:

    • Materials Science
    • Nanotechnology
    • Optics

    Background:

    • Conventional nanopatterning is slow and expensive.
    • Nanoscale textures offer advanced material functionalities.
    • Carbon-fiber-reinforced polymers (CFRPs) are versatile engineering materials.

    Purpose of the Study:

    • To develop a rapid, single-step method for fabricating nanoscale periodic surface textures on CFRPs.
    • To investigate the underlying physics of texture formation.
    • To demonstrate the imparted functionalities for various applications.

    Main Methods:

    • Fabrication of centimeter-scale laser-induced periodic surface structures (LIPSS) using a 355 nm, 10 ps laser.
    • Analysis of LIPSS period dependence on laser polarization.
    • Electromagnetic simulations and experimental validation of the photonic-plasmonic mechanism involving surface plasmon polaritons (SPPs).

    Main Results:

    • Achieved highly uniform LIPSS with a period of approximately 100 nm, dictated by laser polarization.
    • Demonstrated superhydrophilicity (contact angle ≤5°) and increased surface roughness, enhancing adhesion.
    • Observed a significant increase in surface potential and reduced surface resistance, suitable for electronic applications.
    • Confirmed accelerated carrier relaxation dynamics for optoelectronic performance.

    Conclusions:

    • The study presents a scalable, deterministic method for nanopatterning CFRPs using laser-induced periodic surface structures.
    • A photonic-plasmonic mechanism involving SPPs governs the formation of these nanostructures.
    • The resulting textures impart valuable functionalities for enhanced interfacial bonding, electronic devices, and optoelectronic applications.