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Updated: Jan 8, 2026

Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
Light-Induced Orthogonal Reactivity of Photoinitiators from One-Electron Reduction to Nanocomposites
Max Schmallegger1, Mathias Wiech1, Georg Gescheidt1
1Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, Stremayrgasse 9, Graz, A-8010, Austria.
Abstract:
Photoinitiators for radical polymerization have been well established. This minireview indicates a palette of applications beyond their original scope. Depending on the experimental conditions, the primary radicals generated upon photolysis act as reducing agents for metal salts. This opens new possibilities for using photoinitiators as versatile and convenient tools for the preparation of metal/polymer nanocomposites.
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