Related Experiment Video
Updated: Jan 8, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Dimensionality-induced dynamical phase transition in the large deviation of local time density for Brownian motion
1Anhui University, School of Physics, Hefei 230601, China.
Abstract:
We study the fluctuation properties of the local time density, ρ_{T}=1/T∫_{0}^{T}δ(r(t)-1)dt, spent by a d-dimensional Brownian particle at a spherical shell of unit radius, where r(t) denotes the radial distance from the particle to the origin. In the large observation time limit, T→∞, the local time density ρ_{T} obeys the large deviation principle, P(ρ_{T}=ρ)∼e^{-TI(ρ)}, where the rate function I(ρ) is analytic everywhere for d≤4. In contrast, for d>4, I(ρ) becomes nonanalytic at a specific point ρ=ρ_{c}^{(d)}, where ρ_{c}^{(d)}=d(d-4)/(2d-4) depends solely on dimensionality. The singularity signals the occurrence of a first-order dynamical phase transition in dimensions higher than four. Such a transition is accompanied by temporal phase separations in the large deviations of Brownian trajectories. Finally, we validate our theoretical results using a rare-event simulation approach.
Related Concept Videos
Dimensionless Groups in Fluid Mechanics
Third Law of Thermodynamics
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Entropy
Phase Transitions: Vaporization and Condensation
Phase Transitions

