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Updated: Jul 9, 2026
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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Tuning SF6 affinity via tailoring pore environments in metal-organic frameworks
Jackson Geary1, Caith E McKeown1, Nickolas Gantzler1
1Sandia National Laboratories, Albuquerque, NM 87185, USA. dfsava@sandia.gov.
Chemical Communications (Cambridge, England)
|December 23, 2025
Abstract:
Herein, an investigation into the impact of subtle binding site changes on SF6 affinity is presented by systematically altering the pore environment of MOF-808 via post-synthetic modification with aryl and benzylic fluoride groups. All functionalized derivatives outperform the parent material, with aryl fluorides increasing SF6 uptake fourfold.
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