Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)01:20

Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)

1.6K
Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
1.6K
Spin–Spin Coupling Constant: Overview01:08

Spin–Spin Coupling Constant: Overview

1.4K
In bromoethane, the three methyl protons are coupled to the two methylene protons that are three bonds away. In accordance with the n+1 rule, the signal from the methyl protons is split into three peaks with 1:2:1 relative intensities. The methylene protons appear as a quartet, with the relative intensities of 1:3:3:1.
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
1.4K
Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)01:22

Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

1.4K
Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
The extent of coupling depends on the C‑C bond length, the two H‑C‑C angles, any electron-withdrawing substituents, and the dihedral angle between the involved orbitals. The...
1.4K
Spin–Spin Coupling: One-Bond Coupling01:17

Spin–Spin Coupling: One-Bond Coupling

1.4K
Coupling interactions are strongest between NMR-active nuclei bonded to each other, where spin information can be transmitted directly through the pair of bonding electrons. While nuclei polarize their electrons to the opposite spins, the bonding electron pair has opposite spins. Configurations with antiparallel nuclear spins are expected to be lower in energy. When coupling makes antiparallel states more favorable, J is considered to have a positive value. The one-bond coupling constant, 1J,...
1.4K
Standing Waves in a Cavity01:28

Standing Waves in a Cavity

1.4K
A household microwave and lasers are examples of standing electromagnetic waves in a cavity. When two conducting metal plates are placed parallel at the nodal planes, it creates a cavity where standing waves are formed. The cavity between the two planes is analogous to a stretched string held at the points x = 0 and x = L. Here, the distance 'L' between the two planes must be an integer multiple of half of the wavelength. The wavelengths that satisfy this condition are given by:
1.4K
Hybridization of Atomic Orbitals II03:35

Hybridization of Atomic Orbitals II

47.5K
sp3d and sp3d 2 Hybridization
47.5K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Workplace size and cardiovascular disease subtypes among 11 million Korean wage workers: a nationwide cross-sectional study.

BMC public health·2026
Same author

3D-Mixer-Assisted High-Entropy Doping of LiNiO<sub>2</sub> for Co-Free Ni-Rich Cathodes in Lithium-Ion Batteries.

Advanced science (Weinheim, Baden-Wurttemberg, Germany)·2026
Same author

Welding and brazing fumes and lung cancer risk: a systematic review and meta-analysis.

Journal of occupational medicine and toxicology (London, England)·2026
Same author

Matrix-guided embryo-like invasion enables 3D heart organoids with atrioventricular synchrony-like contraction.

Biomaterials·2026
Same author

The therapeutic potential of Myoki, a novel peptide in muscle atrophy: mechanisms and applications.

Frontiers in pharmacology·2026
Same author

Cohort profile: the KDCA-Tuberculosis-NHIS cohort linking tuberculosis surveillance and health insurance data in Korea.

Epidemiology and health·2025

Related Experiment Video

Updated: Jan 8, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

9.6K

Optical Vortex Harmonic Generation Enabled by Confinement-Induced Photonic Spin-Orbit Coupling.

Chang Kyun Ha1, Eun Mi Kim1, Kyoung Jun Moon1

  • 1Department of Physics, Korea Advanced Institute of Science and Technology, 291 Daehak-ro, Yuseong-gu, Daejeon 34141, Republic of Korea.

Nano Letters
|December 24, 2025
PubMed
Summary

Researchers demonstrated novel nonlinear frequency conversion using photonic spin-orbit coupling in optical nanofibers. This breakthrough enables efficient generation of optical vortices, crucial for advanced nanophotonics and all-optical switching.

Keywords:
Confinement-induced spin−orbit couplingHarmonic generationMultimode optical nanofiberNonlinear wave mixingOptical vortices

More Related Videos

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

8.9K
Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators
09:23

Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators

Published on: May 30, 2014

14.9K

Related Experiment Videos

Last Updated: Jan 8, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

9.6K
A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

8.9K
Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators
09:23

Quantum State Engineering of Light with Continuous-wave Optical Parametric Oscillators

Published on: May 30, 2014

14.9K

Area of Science:

  • Nanophotonics
  • Nonlinear Optics
  • Quantum Optics

Background:

  • Photonic spin-orbit coupling (SOC) is significant in subwavelength waveguides, leading to spin-orbit entanglement.
  • The role of confinement-induced SOC in nonlinear optical processes is largely unexplored.
  • Conventional nonlinear optics typically requires specific conditions or materials.

Purpose of the Study:

  • To experimentally demonstrate and theoretically analyze nonlinear optical frequency conversion driven by confinement-induced SOC.
  • To explore the generation of structured light, specifically optical vortices, using this phenomenon.
  • To investigate the potential for ultrafast all-optical switching applications.

Main Methods:

  • Utilizing a silica optical nanofiber as the waveguide medium.
  • Pumping the nanofiber with a spin-polarized Gaussian laser beam.
  • Applying theoretical analysis to understand the underlying physics of the nonlinear process.

Main Results:

  • Successfully generated a third-harmonic optical vortex with orbital angular momentum.
  • Achieved an outcome typically forbidden in isotropic media under conventional nonlinear optical conditions.
  • Demonstrated simple, cost-effective generation of optical vortices without specialized pump beams or materials.

Conclusions:

  • Confinement-induced SOC enables unconventional nonlinear optical frequency conversion.
  • This method provides a new route for generating optical vortices and enabling ultrafast all-optical switching.
  • Opens avenues for exploring spin-orbit-coupled nanophotonic systems and novel light-matter interactions.