Synthesis and Characterization of Eco-Engineered Hollow Fe₂O₃/Carbon Nanocomposite Spheres: Evaluating Structural,...

This work presents a facile mechano-thermal route for the synthesis of carbon-decorated, hollow, mesoporous α-Fe₂O₃ microspheres. Comprehensive characterization (XRD, XPS, FT-IR, SEM/EDX, TGA, zeta-potential) confirmed the formation of phase-pure hematite with nanoscale crystallites (~19 nm), substantial residual surface carbon (~40 wt%) consistent with Fe-O-C linkages, and a positive surface charge (+15.9 mV). The hierarchical hollow/mesoporous architecture enables fast ion transport and provides extensive interior binding sites, resulting in rapid Pb(II) uptake that reaches 92% removal in ≈15 min at pH 5.0. The adsorption follows a Langmuir isotherm (q_max ≈ 70.6 mg/g) and pseudo-second-order kinetics, indicative of chemisorption coupled to efficient mass transfer into internal sites. The composite also exhibits antibacterial activity against Escherichia coli and Staphylococcus aureus, demonstrating its potential for simultaneous mitigation of heavy metal contaminants and pathogens.