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Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules

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Discrete Patterned Functional Polymeric Nanostructures via Controlled Biaxial Iterative Synthesis.

Baiyang Chen¹, Li Yu¹, Kaiyuan Song¹

¹Key Laboratory of Systems Biomedicine (Ministry of Education), Shanghai Center for Systems Biomedicine, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.

|December 29, 2025

Summary

This summary is machine-generated.

Scientists developed a new controlled biaxial iterative synthesis (CBIS) method for precise polymer structure control. This breakthrough enables the creation of complex patterned polymeric nanostructures with potential applications in medicine and technology.

Keywords:

atomic precision biaxial iterative synthesis controlled optical properties patterned polymeric nanostructures stacking modes

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Area of Science:

Polymer Chemistry
Materials Science
Nanotechnology

Background:

Precise sequence control in natural macromolecules is key to life's complexity.
Existing synthetic methods for polymers achieve uniaxial but not multidirectional sequence control.
Achieving atomic-precision in multidirectional polymer synthesis remains a challenge.

Purpose of the Study:

To develop a robust strategy for atomic-precision control of biaxial chain extension in synthetic polymers.
To investigate the molecular mechanisms of coupling reactions in both uniaxial and biaxial synthesis.
To create novel patterned polymeric nanostructures with tunable properties.

Main Methods:

A controlled biaxial iterative synthesis (CBIS) strategy was developed for liquid-phase synthesis.
Density functional theory (DFT) simulations were used to analyze reaction mechanisms.
CBIS was used to synthesize diverse patterned polyporphyrins (zigzag, J, T, U motifs).

Main Results:

CBIS achieved atomic-precision control over biaxial chain extension.
Diversified patterned polymeric nanostructures were successfully synthesized.
The synthesized polyporphyrins exhibited tunable optical performance and reactive oxygen species generation.

Conclusions:

The CBIS strategy offers unprecedented control over polymer architecture.
Patterned polyporphyrins demonstrate potential for advanced applications in energy, informatics, and pharmaceuticals.
This method opens new avenues for designing complex functional macromolecules.