Influence of the Nd³⁺ Dopant Content in Bi₃TeBO₉ Powders on Their Optical Nonlinearity

Second harmonic generation measurements for neodymium-doped bismuth-tellurium borate (Bi₃TeBO₉:Nd³⁺) powders are shown for the first time. Using undoped and low-content Nd³⁺-doped samples associated with the strongest nonlinear optical response, studies of temperature-dependent second-harmonic generation near the absorption edge were conducted. Spectroscopic measurements of the investigated powders revealed characteristic Nd³⁺ absorption bands and helped to estimate the corresponding energy band gaps for the chosen samples. The influence of low Nd³⁺-content on the absorption edge shift, as well as on the enhancement of second-harmonic generation and its temperature attenuation, is discussed. Temperature-dependent X-ray diffraction measurements enabled researchers to calculate the thermal expansion coefficients for undoped and Nd³⁺-doped Bi₃TeBO₉ and to assess the impact of this phenomenon on its acentricity. Thermogravimetric studies demonstrated the absence of phase transitions for the chosen samples up to their incongruent melting points. Energy Dispersive X-ray Spectroscopy measurements verified the uniformity of Nd³⁺ distribution in doped Bi₃TeBO₉ powders. The suitability of polycrystalline Bi₃TeBO₉:Nd³⁺ as media for the self-frequency doubling devices for potential optoelectronic and biomedical applications was assessed. The finest fractions of deagglomerated and suspended powders were extracted and demonstrated near-nanostructural morphology of separated particles, as revealed by means of atomic force microscopy.