Progress in Charge Transfer in 2D Metal Halide Perovskite Heterojunctions: A Review

Metal halide perovskite (MHP)-based heterojunctions have become a forefront area in the research of optoelectronic functional materials due to their unique layered crystal structure, tunable band gaps, and exceptional optoelectronic properties. Recent studies have demonstrated that interface charge transfer is a crucial factor in determining the optoelectronic performance of the heterojunction devices. By constructing heterojunctions between MHPs and two-dimensional (2D) materials such as graphene, MoS₂, and WS₂, efficient electron-hole separation and transport can be achieved, significantly extending carrier lifetimes and suppressing non-radiative recombination. This results in enhanced response speed and energy conversion efficiency in photodetectors, photovoltaic devices, and light-emitting devices (LEDs). In these heterojunctions, the thickness of the MHP layer, interface defect density, and band alignment significantly influence carrier dynamics. Furthermore, techniques such as interface engineering, molecular passivation, and band engineering can effectively optimize charge separation efficiency and improve device stability. The integration of multilayer heterojunctions and flexible designs also presents new opportunities for expanding the functionality of high-performance optoelectronic devices. In this review, we systematically summarize the charge transfer mechanisms in MHP-based heterojunctions and highlight recent advances in their optoelectronic applications. Particular emphasis is placed on the influence of interfacial coupling on carrier generation, transport, and recombination dynamics. Furthermore, the ultrafast dynamic behaviors and band-engineering strategies in representative heterojunctions are elaborated, together with key factors and approaches for enhancing charge transfer efficiency. Finally, the potential of MHP heterojunctions for high-performance optoelectronic devices and emerging photonic systems is discussed. This review aims to provide a comprehensive theoretical and experimental reference for future research and to offer new insights into the rational design and application of flexible optoelectronics, photovoltaics, light-emitting devices, and quantum photonic technologies.