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Related Concept Videos

P-N junction01:11

P-N junction

A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...

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Multidentate Chelation by Imine-Linked Covalent Organic Framework Enables High-Performance Tin-Based Perovskite Solar

Wei Huang1,2, Tianpeng Li3, Hao Luo1,2

  • 1Beijing National Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China.

Advanced Materials (Deerfield Beach, Fla.)
|January 3, 2026
PubMed
Summary

Tin-based perovskite solar cells (TPSCs) show promise, but tin oxidation limits performance. Novel covalent organic frameworks (COFs) were used as additives to suppress oxidation and passivate defects, enhancing TPSC efficiency and stability.

Keywords:
covalent organic frameworksdefect passivationenergy level alignmentpower conversion efficienciestin‐based perovskite solar cell

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Area of Science:

  • Materials Science
  • Renewable Energy
  • Photovoltaics

Background:

  • Tin-based perovskite solar cells (TPSCs) offer eco-friendliness and high efficiency potential.
  • Sn2+ oxidation in TPSCs leads to defects, hindering charge transport and device performance.

Purpose of the Study:

  • To investigate the use of imine-linked donor-acceptor covalent organic frameworks (COFs) as precursor additives in TPSCs.
  • To address Sn2+ oxidation and defect passivation challenges in tin-based perovskite solar cells.

Main Methods:

  • Synthesized and utilized two COFs, BCTB-BTD-COF and BCTB-BSD-COF, as additives in TPSC fabrication.
  • Evaluated the impact of COFs on Sn2+ oxidation suppression, defect passivation, and device performance metrics.

Main Results:

  • Both COFs effectively suppressed Sn2+ oxidation and passivated defects.
  • BCTB-BSD-COF demonstrated superior performance via multidentate chelation, improving defect passivation and energy-level alignment.
  • TPSCs with BCTB-BSD-COF achieved a champion power conversion efficiency of 16.29% and retained 85% efficiency after 35 days.

Conclusions:

  • Covalent organic frameworks (COFs) present a novel strategy for defect passivation in tin-based perovskite solar cells.
  • The use of BCTB-BSD-COF as an additive significantly enhances TPSC performance and stability.
  • This approach offers a promising route towards high-efficiency and stable tin-based perovskite solar cells.