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Simple Optical Fiber Sensor for Express and Cross-Sensitive Hydrogen Detection.

Elena Miliutina1,2, Yuliia Viktosenko1, Andrii Trelin1

  • 1Department of Solid State Engineering, University of Chemistry and Technology, 166 28 Prague, Czech Republic.

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|January 7, 2026
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Summary
This summary is machine-generated.

A new optical hydrogen sensor uses a plasmon-active fiber coated with palladium and PDMS layers. This sensor offers fast, reliable hydrogen detection with protection against interfering gases and humidity.

Keywords:
PDMSPdhydrogen detectionoptical fiberplasmon

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Area of Science:

  • Materials Science
  • Sensor Technology
  • Optical Engineering

Background:

  • Growing use of hydrogen as an energy source necessitates robust, inexpensive hydrogen sensors.
  • Existing sensors often lack crucial features like small size, corrosion resistance, and immunity to interfering factors.
  • Key sensor parameters include sensitivity, selectivity, stability, and remote operation capability.

Purpose of the Study:

  • To develop a simple, cost-effective optical hydrogen sensor meeting critical performance criteria.
  • To investigate the efficacy of a plasmon-active optical fiber coated with palladium and PDMS for hydrogen sensing.
  • To evaluate the sensor's response time, regeneration, operating temperature range, and resistance to environmental factors.

Main Methods:

  • Fabrication of a sensor using a plasmon-active multimode optical fiber.
  • Stepwise coating of the fiber with palladium (Pd) and polydimethylsiloxane (PDMS) layers.
  • Utilizing the shift in plasmon absorption band wavelength due to Pd hydrogenation for hydrogen detection.
  • Testing sensor performance with various interfering gases (NO2, CH4, CO2, CO, NH3) and humidity.

Main Results:

  • The Pd layer facilitates hydrogen detection via hydrogenation, causing a significant wavelength shift in the plasmon absorption band.
  • The additional PDMS layer effectively protects the sensor from interfering gases and moisture.
  • The sensor exhibits a rapid response time (tens of seconds) and a regeneration time of approximately 2 minutes.
  • The sensor operates effectively from room temperature to 80 °C, with a minor performance decrease at higher temperatures.

Conclusions:

  • The developed optical fiber sensor is a simple and effective solution for hydrogen detection.
  • The sensor meets key requirements for practical hydrogen sensing applications, including speed, protection, and operational range.
  • This technology holds promise for safe and widespread hydrogen utilization.