Extraction of Yttrium from Waste: Analysis of Hydrometallurgical Processing by Organic Acids and Life Cycle...

The increasing demand for rare earth elements has driven the search for efficient and sustainable recovery methods. Obsolete fluorescent lamps represent a significant secondary source of Y that can greatly contribute to the circular economy and the preservation of natural resources. With the gradual depletion of primary Y reserves and the rise in e-waste generation, the development of eco-friendly and economically feasible recovery techniques has become crucial. Additionally, strict legislation regarding the disposal of e-waste strengthens the need to improve recycling processes. This study aims to investigate the leaching of Y from obsolete fluorescent lamps by organic (C₆H₈O₇, C₂H₄O₂, and C₂H₅NO₂) and inorganic acids (HNO₃). We also seek to assess the environmental impact of this process through life cycle assessment (LCA). Leaching steps were performed with different acid concentrations, followed by selective precipitation with C₂H₂O₄ for Y recovery. LCA was applied to evaluate the environmental impacts and identify critical points in the process. A high Y recovery rate (78.8% for C₂H₅NO₂, 86.7% for C₆H₈O₇, 100% for C₂H₄O₂, and 95% for HNO₃) was obtained with precipitation (C₂H₅NO₂ and C₆H₈O₇ liquor). Our environmental assessment revealed that leaching with organic acids presents a higher environmental impact due to production and disposal methods. The study demonstrated that it is possible to leach Y efficiently from fluorescent lamps using organic acids. The process may be a feasible alternative for large-scale Y recovery, improving organic acid production, and contributing to the sustainable recycling of e-waste and promoting the circular economy.