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Large Capacitive Energy Storage in Linear-Like MLCCs with Tailored Atomic-Scale Polymorphic Polarization

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Entropy engineering in lead-free multilayer ceramic capacitors (MLCCs) creates atomic-scale disorder, enhancing energy storage. This approach yields high recoverable energy density and efficiency for advanced electronic devices.

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energy densityentropylinear‐like polarizationmultilayer ceramic capacitor

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Ceramics Engineering

Background:

  • Growing demand for portable electronics necessitates advanced energy storage solutions.
  • Lead-free multilayer ceramic capacitors (MLCCs) are crucial components requiring improved energy storage capabilities.

Purpose of the Study:

  • To develop a novel strategy for enhancing the energy storage properties of lead-free MLCCs.
  • To investigate the effects of entropy engineering on atomic-scale polarization and material performance.

Main Methods:

  • Entropy engineering was employed to induce atomic-scale lattice disorder.
  • Polymorphic polarization fluctuations were generated by increasing entropy, leading to coexisting rhombohedral and tetragonal phases.
  • Polar anisotropy and domain switching barriers were significantly reduced.

Main Results:

  • A giant recoverable energy density (Wrec) of 21.3 J·cm⁻³ was achieved at 1045 kV·cm⁻¹.
  • High energy efficiency (η) of 94.5% was observed.
  • The high-entropy MLCC demonstrated excellent broad-temperature, frequency, and cyclic stability.

Conclusions:

  • Entropy engineering is an effective approach for designing superior-performing lead-free MLCCs.
  • The study reveals a critical entropy-structure-performance correlation for MLCC development.
  • This work offers a reliable technical strategy for next-generation energy storage devices.