Electric Field-Driven Melt Jetting Polycaprolactone Rotational Printing of Fully Degradable Vascular Stents and...

Addressing technical challenges in personalized fabrication and mechanical regulation of bioresorbable vascular scaffolds, this study pioneers an electric field-driven melt jetting rotational printing technique to fabricate polycaprolactone (PCL) scaffolds (Ø3-8 mm). Multiscale characterization confirms a rhombic mesh macrostructure with uniform fibers and fusion-enhanced nodal junctions, demonstrating synergistic control of electrohydrodynamic forces and surface tension over microfiber deposition. Mechanical testing reveals triphasic tensile behavior (elastic-plastic-fracture), where 5 mm scaffolds exhibit 38% enhanced peak load due to superior interfacial bonding and densified geometry, while 8 mm counterparts suffer premature failure from structural weakening. Fractography identifies brittle fracture initiation at stress-concentrated nodes versus ductile dominance in straight segments, confirming co-regulation by intrinsic material properties and architecture. Compression tests demonstrate characteristic load-holding-recovery behavior, with 20% increased load-bearing capacity and enhanced elastic recovery in larger scaffolds. This work establishes a structure-property correlation framework for optimizing degradable vascular implants, providing novel methodologies and theoretical foundations for clinical compatibility.