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Updated: Jan 17, 2026

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Synthesis and Characterization of Amphiphilic Gold Nanoparticles
Published on: July 2, 2019
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β-Vinylated Tri(1-adamantyl)phosphine: Synthesis, Characterization, and Application in Gold Catalysis
Aituar Tulipkaliyev1, Masaya Sawamura1,2, Yusuke Masuda1
1Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, Hokkaido, Japan.
Chemistry, an Asian Journal
|January 14, 2026
Abstract:
A β-vinylated tri(1-adamantyl)phosphine was synthesized from tri(1-adamantyl)phosphine through a photocatalytic cycloaddition/base-induced elimination sequence. The electronic and steric properties of the new phosphine were examined through structural characterization of its chalcogenides and gold complex. The gold complex catalyzed hydroamination of alkynes, demonstrating its potential in transition metal catalysis.

