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Steering photoinduced multi-electron accumulation via high-concentration sacrificial electron donors
Rui Jing1, Yuhang Yang1, Junji Zhao1
1State Key Laboratory of Information Photonic and Optical Communications, and School of Physical Science and Technology, Beijing University of Posts and Telecommunications (BUPT), Beijing 100876, P. R. China. songdi@bupt.edu.cn.
None:
Efficient artificial photosynthesis requires rapid, sequential multi-electron transfer and accumulation. This work demonstrates a kinetic strategy for efficient two-electron accumulation, leveraging high-concentration sacrificial electron donors. Transient spectroscopy confirms that pseudo-first-order reduction of the perylene diimide radical anion excited state (PDI˙-*) outcompetes its intrinsic deactivation, enabling long-lived PDI2- generation.
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