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This study introduces an alternative density functional theory (DFT) scheme using the Lovett-Mou-Buff-Wertheim (LMBW) equation. This method minimizes structural inconsistencies between thermodynamic routes for inhomogeneous fluids.

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Area of Science:

  • Physical Chemistry
  • Statistical Mechanics
  • Computational Physics

Background:

  • Classical density functional theory (DFT) is crucial for studying inhomogeneous fluids under external fields.
  • DFT relies on the excess Helmholtz free energy functional and the Euler-Lagrange equation.
  • Force-DFT, a variant, uses the Yvon-Born-Green equation, aligning with the virial thermodynamic route.

Purpose of the Study:

  • To present an alternative DFT scheme utilizing the Lovett-Mou-Buff-Wertheim (LMBW) equation.
  • To demonstrate the consistency of the LMBW DFT with the compressibility route of thermodynamics.
  • To explore an optimization scheme for minimizing structural inconsistencies between thermodynamic routes.

Main Methods:

  • Implementation of an alternative DFT scheme based on the Lovett-Mou-Buff-Wertheim (LMBW) equation.
  • Utilizing a closure relation on the level of two-body correlation functions for both force-DFT and LMBW DFT.
  • Numerical simulations for density profiles of 2D hard-core Yukawa systems in planar geometry.

Main Results:

  • The LMBW DFT scheme is shown to be consistent with the compressibility route for thermodynamics.
  • Both force-DFT and LMBW DFT can be implemented using a closure relation on two-body correlation functions.
  • Numerical results demonstrate density profiles for 2D systems with repulsive or attractive Yukawa tails.

Conclusions:

  • The proposed LMBW DFT offers an alternative consistent with the compressibility route.
  • The shared implementation feature of force-DFT and LMBW DFT enables minimization of structural inconsistencies.
  • This approach provides a unified framework for studying inhomogeneous fluids, optimizing density profile calculations.