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Self-Propulsion via Nontransitive Phase Coexistence in Chemically Active Mixtures.
Yicheng Qiang1, Chengjie Luo1, David Zwicker1
1Max Planck Institute for Dynamics and Self-Organization, Am Faßberg 17, 37077 Göttingen, Germany.
Chemical reactions in active matter mixtures drive phase separation by altering chemical potential and osmotic pressure. This non-transitive phase coexistence enables self-propulsion and complex dynamics in these systems.
Area of Science:
- Active matter physics
- Chemical kinetics
- Soft condensed matter
Background:
- Chemical activity is key in active matter, influencing self-propulsion and phase separation.
- Phase separation can also arise from passive physical interactions, complicating the role of chemical activity.
Purpose of the Study:
- To investigate how chemical reactions, specifically interconverting solvent species and segregating solutes, influence phase separation in active matter.
- To understand the interplay between chemical potential, osmotic pressure, and phase behavior.
Main Methods:
- Studying mixtures with interconverting solvent species and segregating solutes.
- Analyzing the effects of chemical reactions on chemical potential balance and osmotic pressure at interfaces.
Main Results:
- Chemical reactions alter the chemical potential balance and create osmotic pressure differences at interfaces, driving phase separation.
- The system exhibits non-transitive phase coexistence, where bulk compositions depend on contacting phases.
Conclusions:
- Chemical activity significantly impacts phase separation dynamics in active matter beyond passive interactions.
- Non-transitive phase coexistence, enabled by chemical reactions, leads to emergent behaviors like self-propulsion and complex dynamics.
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