Processes of Thermal Treatment on Hazelnuts Investigated by NMR and MRI

  • 0Institute of Mechanical Process Engineering and Mechanics, KIT, Karlsruhe, Germany.

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Summary

This summary is machine-generated.

Nuclear Magnetic Resonance (NMR) and Magnetic Resonance Imaging (MRI) monitored hazelnut roasting. High temperatures destroyed oil-containing structures and initiated oil oxidation, impacting product quality.

Area Of Science

  • Food Science and Technology
  • Analytical Chemistry
  • Materials Science

Background

  • Hazelnuts have a high oil content crucial for quality and shelf life.
  • Thermal processing, like roasting, can negatively impact hazelnut oil stability and structure.
  • Understanding these changes is vital for optimizing processing and ensuring product quality.

Purpose Of The Study

  • To monitor structural and compositional changes in hazelnuts during thermal treatment using NMR and MRI.
  • To investigate the roasting and aging behavior of hazelnut oil.
  • To correlate changes across molecular, micro-, and mesostructural levels.

Main Methods

  • In situ Magnetic Resonance Imaging (MRI) for mesostructural analysis (50 μm - mm).
  • Pulsed Field Gradient Stimulated Echo (PFG-STE) NMR diffusion experiments for microstructural analysis (100 nm - 10 μm).
  • NMR spectroscopy for molecular-level analysis of oil oxidation.

Main Results

  • MRI revealed significant void formation and cellular collapse at 200°C during roasting.
  • PFG-STE NMR showed oleosome destruction at 100°C and altered oil mobility.
  • NMR spectroscopy indicated temperature-dependent oxidation of unsaturated fatty acids in hazelnut oil.

Conclusions

  • Combined MRI and NMR enable quasi-nondestructive, in situ monitoring of hazelnut transformations during thermal processing.
  • Thermal stress significantly alters hazelnut microstructure and oil composition, affecting quality.
  • These techniques provide valuable insights into hazelnut oil behavior under processing conditions.

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