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Updated: Jan 27, 2026

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Published on: September 18, 2018
Substituent effect on the boron atoms in boron-bridged hexazenes
Masahiro Yamamoto1, Makoto Yamashita1
1Department of Chemistry, School of Science, Institute of Science Tokyo, 2-12-1, Ookayama, Meguro-ku, Tokyo, 152-8551 Japan. yamashita.m.6dbb@m.isct.ac.jp.
Abstract:
This work investigates the substituent effect on the boron atom toward the electronic structure and optical properties of boron-bridged hexazene derivatives (B2N6). DFT studies revealed that the substituents on the boron atom strongly affect the energy level of the N6-centered π system and alter the absorption/emission spectra. In addition, cyclic voltammetry demonstrates the electron-accepting character of the B2N6 scaffold.
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