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Published on: April 3, 2016
Self-Assembling Conjugated Organic Materials with a Silazane Anchor Group: Synthesis, Self-Organization, and
Elizaveta A Bobrova1,2, Maxim S Skorotetсky1, Bogdan S Kuleshov1
1Enikolopov Institute of Synthetic Polymer Materials of the Russian Academy of Sciences, Profsoyuznaya Str. 70, 117393 Moscow, Russia.
None:
An efficient synthetic method for the preparation of self-assembling conjugated organic materials with a silazane anchor group based on direct hydrosilylation reaction is reported. A novel organic semiconductor molecule, NH(Si-Und-BTBT-Hex)2, consisting of a polar silazane anchor group linked through undecylenic (Und) aliphatic spacers to conjugated blocks based on benzothieno[3,2-b][1]benzothiophene (BTBT) and solubilizing hexyl (Hex) end groups, was synthesized. Its self-organization on the air-water interface and solid substrates into ultrathin layers obtained by the Langmuir-Schaefer or Langmuir-Blodgett methods was investigated. Monolayer organic field-effect transistors manufactured from NH(Si-Und-BTBT-Hex)2 showed operation in the p-type mode.
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