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Abiotic sugar enantiomers in the CI carbonaceous chondrite Orgueil
Vanessa Leyva1, Manuel Robert1, Raphaël Pepino1
1Université Côte d'Azur, Institut de Chimie de Nice, UMR 7272 CNRS, Nice, France.
Abstract:
The uneven detection of prebiotic organic compounds in meteorites-where amino acids and nucleobases are commonly identified but sugars remain rare and poorly characterized-limits our understanding of extraterrestrial organic chemistry. This discrepancy is striking given that laboratory simulations of interstellar ice chemistry readily produce complex sugars. Here we report the simultaneous analysis of sugar and amino acid enantiomers in a meteorite sample. Multiple aldoses were detected in the Orgueil meteorite, including ribose, arabinose, xylose, lyxose, and the ketopentose ribulose, several of which display near-racemic distributions consistent with an extraterrestrial origin. Recovery experiments demonstrate that sugar abundances are severely underestimated. Despite this limitation, pentose abundances are comparable to those of some C4-C5 amino acid enantiomers, implying higher true concentrations. These results indicate efficient abiotic sugar formation in space and suggest that meteorites may have delivered a broader range of prebiotically relevant sugars to early Earth than previously recognized.
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Stereoisomerism
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...

