Long-Lasting Hydrophilicity of Al₂O₃ Surfaces via Femtosecond Laser Microprocessing

We explore the wettability modulation induced on alumina (Al₂O₃) targets by femtosecond laser texturing to demonstrate the stable and durable hydrophilic character of the surface. Specifically, we identify a suitable operational regime to tailor micro-nanostructures onto Al₂O₃ plates and accurately assess the ablation threshold in our experimental conditions. A periodic geometry with triangular patterns of various groove depths, ranging from 3.2 ± 0.1 to 17.1 ± 0.1 µm, was optimized for establishing a long-term wetting response. The latter was monitored on daily basis over a time interval exceeding 40 days by collecting the contact angle measurements of samples with and without a post-process thermal annealing, adopted to stabilize the surface wettability soon after the laser treatment. The results show that deeper grooves significantly enhance and maintain the hydrophilic character, particularly in samples without post-process thermal annealing, where superhydrophilicity (θ < 5°) is demonstrated to persist the entire time throughout the test. These findings disclose the potential for an effective fine-tuning of the alumina wettability, thus opening up the possibility of specific applications requiring long-term control of surface-liquid interactions, such as biomedical implants, and orthopedic and dental prostheses.