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Published on: March 14, 2025
Nitrogen-centred helical acridiniums with a 6-7-6-6 fused ring skeleton
Shuto Nakamura1, Soki Kawaguchi1, Yuta Nishimura1
1Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan. yishigaki@sci.hokudai.ac.jp.
Abstract:
Helical 6-7-6-6 fused acridiniums were synthesised via oxidative ring contraction of a helical azaheptalene. X-ray, spectroscopic, and theoretical studies revealed highly distorted, configurationally stable helicity with long-wavelength absorption and chiroptical properties. These findings provide a new π-conjugated helical framework for functional chiral materials.
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