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Updated: Jan 31, 2026

Interfacial Molecular-level Structures of Polymers and Biomacromolecules Revealed via Sum Frequency Generation Vibrational Spectroscopy
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Engineering Interfacial Donor-Acceptor Molecular Cocrystals.

Nikolai Severin1,2, Neda Todorova2,3, Tomáš Neveselý2,3

  • 1Department of Physics, Humboldt-Universität zu Berlin, 12489 Berlin, Germany.

The Journal of Physical Chemistry Letters
|January 29, 2026
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Summary
This summary is machine-generated.

Researchers explored how Y6 molecules assemble at interfaces using scanning tunneling microscopy. Coadsorption with donor molecules formed ordered cocrystals, crucial for advancing organic solar cell performance.

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Area of Science:

  • Materials Science
  • Organic Electronics
  • Surface Science

Background:

  • Y6 is a key non-fullerene acceptor in organic solar cells.
  • Its interfacial assembly behavior is poorly understood.
  • In-depth studies are needed to optimize device performance.

Purpose of the Study:

  • Investigate the self-assembly of Y6 at solid-liquid interfaces.
  • Understand how Y6 interacts with donor molecules.
  • Explore the formation of interfacial cocrystals.

Main Methods:

  • Utilized room-temperature scanning tunneling microscopy (STM).
  • Studied Y6 self-assembly on a graphite surface.
  • Examined coadsorption with polycyclic aromatic hydrocarbon donor molecules.

Main Results:

  • Demonstrated the formation of donor-acceptor interfacial cocrystals.
  • Showcased tailored molecular structures and order within cocrystals.
  • Revealed the interplay of intermolecular forces driving assembly.

Conclusions:

  • Gained insights into Y6 interfacial assembly.
  • Facilitated engineering of multicomponent interfacial nanostructures.
  • Aimed to improve charge separation and transport in organic optoelectronics.