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High Power Density for All-Fe2VAl-based Thermoelectric Module by Enhancing the Power Factor of p-type Leg Through
Tarachand1, Naohito Tsujii1, Raju Chetty1
1Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Japan.
Small Methods
|February 2, 2026
Summary
Researchers enhanced the thermoelectric performance of iron-based compounds (Fe2Al) using defect engineering and a novel wetting effect. This resulted in a record-breaking power density for thermoelectric devices near room temperature.
Area of Science:
- Materials Science
- Solid State Physics
- Thermoelectrics
Background:
- Iron-based compounds (Fe2Al) exhibit promising thermoelectric properties due to their electronic band structure.
- Improving the performance of p-type Fe2Al has been challenging compared to n-type.
- Reproducibility and scale-up issues hinder practical applications.
Purpose of the Study:
- To enhance the p-type thermoelectric performance of Fe2Al through defect and grain boundary engineering.
- To develop a low-resistance contact method for Fe2Al thermoelectric legs.
- To achieve high output power density in Fe2Al-based thermoelectric modules.
Main Methods:
- Regulating the V/Al ratio and incorporating In-doping in Fe2V0.85Ti0.1Ta0.05Al.
- Utilizing a wetting effect to improve the power factor near room temperature.
- Implementing a two-step metallization process for p- and n-type Fe2Al legs.
Main Results:
- Significant enhancement in power factor achieved near room temperature via the wetting effect.
- Achieved significantly low contact resistance for both p- and n-type Fe2Al.
- Demonstrated a high output power density of 624 mW/cm2 with ΔT = 327 K in an All-Fe2Al module, 3.8 times higher than previous records.
Conclusions:
- A novel approach using the wetting effect successfully boosted p-type Fe2Al thermoelectric performance.
- The developed metallization process minimizes contact resistance, maximizing power output.
- High power density, material stability, and abundance make Fe2Al a viable candidate for power generation and cooling applications.
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