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Updated: Feb 4, 2026

Synthesis of Platinum-nickel Nanowires and Optimization for Oxygen Reduction Performance
Published on: April 27, 2018
Surface-composition-driven patchy carbon shells unlock high activity and durability in PtCu oxygen reduction
Hyelim Park1, Keonwoo Ko1, Yunjin Kim1
1Graduate School of Energy Science and Technology (GEST), Chungnam National University, 99 Daehak-ro, Yuseong-gu, Daejeon 34134, Republic of Korea. cosy32@cnu.ac.kr.
Abstract:
Low-temperature CO treatment induces Pt surface segregation in carbon-incorporated PtCu nanoparticles, creating Pt-rich surface domains that localize carbon growth. Subsequent high-temperature Ar treatment forms a patchy carbon shell, enabling selective near-surface Cu dealloying, boosting oxygen reduction reaction (ORR) activity while suppressing particle degradation and markedly improving durability.
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